A good installation of DarqUI doesn't require you to use /loadui each time you start the game. The /loadui command is disruptive and should only be used rarely, for example to diagnose a problem with the UI.
Log completely out of the game, and then in the DarqUI utility on the Files page click the blue link for "Make this UI the default." If the link says "Stop using this UI as the default" then click it twice: once to clear the setting and then a second time to set DarqUI.
Log back in to the game and you should see DarqUI immediately without using a command. If you see the default UI, it may mean there is a file permission or read-write problem within your EverQuest II game folder or utility location.
In your exception text it shows the utility as running on the B: drive which is unusual. Are you using a VM or Microsoft OneDrive or other cloud sync service that may be affecting your game folder and/or your DarqUI utility?
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