You'll only get "Change Icon Size" when clicking on a Hotbar. I'm not sure if every mod has it, or if its FetishNightfall specific.
Also, try going in Window Settings and uncheck "Locked" there.
Some UIs might (for some reason) try and prevent you from moving windows by coding it in. If you want to, try looking and the code and see if you can find "UserMoveable='false'" in the windows that you can't seem to move.
The default is generally like you said -- chat at the bottom left, most stuff on the top.
Which UI are you really having trouble with? Is it ProfitUI or ThorUI, or another perhaps?
EDIT: One last thing. You can't always move windows by just anywhere. Most windows you have to drag the title bar in order to move them. Also, some windows might have "Click-through enabled" in the WindowSettings: uncheck that box so that its disabled and you should be able to move those windows then.
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