What window are you referring to when you say debuff?
The Maintained (alt+m) or Effects (alt+e) ?
Maintained windows already have the ability to show timers, and there are several such mods here in the downloads section. For the Effects window, that info is not provided, so such a mod can't be made, as I understand it.
As for changing icon size, I don't think that's possible at all.
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